Process for the manufacture of tertiary, optically active alipha

Details Process for the manufacture of tertiary, optically active alipha Process for the manufacture of tertiary, optically active alipha

1978-11-24

1981-12-15

Love, Ethel G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603455, 2603456, 2603459R, 560174, 560180, 560226, 560179, 568 9, 568382, 568495, 568678, 568840, 570101, 570217, 570261, C07D30732, C07C 6966, C07C 4310

Patent

active

043058760

ABSTRACT:
A process for asymmetrically hydrogenating through the use of microorganisms a double bond connected to tertiary carbon atom in an olefinic aliphatic compound to produce a tertiary, optically active aliphatic compound useful as an intermediate for optically active Vitamins E and K.

REFERENCES:
patent: 4051153 (1977-09-01), Cohen et al.
patent: 4191842 (1980-03-01), Cohen et al.
Krezdorn et al., Hoppe Seyler's, Z. Physiol. Chem., 1977, 358(8), pp. 945-948.
Craig et al., Tetrahedron, 33 pp. 183-190, Feb. 1977.
Korver et al., Tetrahedron 31, pp. 2603-2606, 1975.
Chem. Abstract 87:66556p (1977).
Chem. Abstracts 70:58052e.
Chem. Abstracts: 86:140123t and 86:189100x.
Chem. Abstracts 76:24540w.
Chem. Abstracts 83:147356t.
Chem. Abstracts 78:111531d (p. 8480cs, 9th Coll.).
Chem. Abstracts 80:15929k.
Chem. Abstracts 85:198042n.
Chem. Abstracts 84:146834f (p. 8446cs, 9th Coll.).
Chem. Abstracts, 1972-1976, Chem. Substance Index, "dihydro-3-methyl-2(3H)furanone", p. 16777cs.
Chem. Abstracts: 98715d.

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