Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1986-06-10
1987-08-25
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 7936
Patent
active
046894330
ABSTRACT:
A process for the manufacture of o-nitrobenzaldehyde by oxidation of o-nitrotoluene, characterized in that o-nitrotoluene is made to react with an aqueous solution containing Cerium.sup.iv perchlorate and from 5 to 9 moles/liter of perchloric acid; according to a preferred embodiment, the dispersion of o-nitrotoluene in an aqueous solution containing from 5 to 9 moles per liter of perchloric acid is first prepared and then an aqueous solution is gradually added, containing Cerium.sup.iv perchlorate and 5-9 moles/liter of perchloric acid.
REFERENCES:
Syper, Tetrahedron Letters, No. 37 (1966), 4493-4498.
Foa Marco
Gatti Norberto
Lone Werren B.
Montedison S.p.A.
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