Process for the manufacture of monomethyl-tin trichloride

Details Process for the manufacture of monomethyl-tin trichloride Process for the manufacture of monomethyl-tin trichloride

1974-08-07

1976-07-27

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07F 722

Patent

active

039718174

ABSTRACT:
In the manufacture of monomethyl-tin trichloride by disproportionation of tin tetrachloride with dimethyl-tin dichloride, high yields are achieved by employing phosphines, arsines and stibines or onium compounds of elements of the fifth main group in the periodic system as the catalyst, optionally together with a co-catalyst.

REFERENCES:
patent: 3297732 (1967-01-01), Banks
patent: 3414595 (1968-12-01), Oakes
patent: 3415857 (1968-12-01), Hoye
patent: 3454610 (1969-07-01), Langer
patent: 3459779 (1969-08-01), Neumann
patent: 3519665 (1970-07-01), Molt et al.
patent: 3519667 (1970-07-01), Molt et al.
patent: 3595892 (1971-07-01), VAN DEN Hurk
patent: 3824264 (1974-07-01), Bulten
patent: 3862198 (1975-01-01), Kugele et al.
Chemical Abstracts vol. 63, 11599h (1965).
J. Organometal. Chem., vol. 6 pp. 522-527 (1966).

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