Process for the manufacture of mixed phosphoric acid ester compo

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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260964, 260965, C07F 909

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044380488

ABSTRACT:
Mixed phosphoric acid ester compositions containing by weight less than 4% of a triaryl phosphate; from about 30% to about 35% of an aryl dialkoxyalkyl phosphate and from about 60% to about 65% of an alkoxyalkyl diaryl phosphate are prepared by heating an alkoxy alcohol with aqueous sodium hydroxide to form the sodium alkoxide, distilling off the water as an alkoxy alcohol azeotrope and reacting the alkoxy alcohol sodium alkoxide with a triphenyl phenol. The mixed phosphoric acid ester composition may be separated from by-products of the reaction by distillation.

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W. H. C. Rueggeberg et al. in J. Am. Chem. Soc. 70. 1802, (1948).
Chemical Abstract of Polish Patent 78616.

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