Process for the manufacture of homo- and copolymers of tetrafluo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 88, 526 91, 526 78, 526201, 526217, 526220, 526255, C08F 404, C08F 440, C08F 1418, C08F11418

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041122119

ABSTRACT:
Polymers on the basis of tetrafluoroethylene are produced in the presence of a redox system as catalyst consisting of a usual peroxidic compound as oxidizing component and a water-soluble nitrogen compound liberating in situ a diimine under the polymerization conditions. The polymers obtained can be processed, inter alia, into thick walled articles on a ram extruder or into large sintered block free from crack formation.

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patent: 3110704 (1963-11-01), Halliwell
patent: 3142665 (1964-07-01), Cardinal et al.
patent: 3193543 (1965-07-01), Ragazzini et al.
patent: 3404135 (1968-10-01), Tietz
patent: 3475391 (1969-10-01), Coker
patent: 3939134 (1976-02-01), Console et al.

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