Process for the manufacture of fatty acid nitriles and glycerol

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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568852, 568869, C07C12000, C07C12008, C07C12010

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active

042345090

ABSTRACT:
Glycerol and aliphatic nitriles are simultaneously produced by treating liquid glycerides with gaseous ammonia at a rate of at least 200 liters of ammonia per kilogram of glyceride per hour at temperatures of from 220.degree. to 300.degree. C. in the presence of metal salts of carboxylic or sulfonic acids as catalysts and subjecting the product mixture to a phase separation into a nitrile phase and a glycerol/water phase. Preferred starting materials are vegetable and animal fats and oils.

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patent: 2794043 (1957-05-01), Jansen et al.
patent: 2808426 (1957-10-01), Potts et al.
patent: 2993926 (1961-07-01), Stenberg et al.
patent: 3850974 (1974-11-01), Lichtenwalter et al.
Handbook of Tables for Organic Compound Identification, 3rd Ed., Rappoport, 1967, p. 86, The Chem. Rubber Co.
Hauschild et al., C. A., 50, 1958, 14243-f.
Ullmanns Encyklopodie der Technischen Chemie, 4th Ed., 1976, vol. 12, pp. 367-368.

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