Process for the manufacture of extremely pure monoethylene glyco

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

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203 36, 203 37, 203 38, 203 71, 568867, 568868, B01D 334, C07C 2980, C07C 3120

Patent

active

043494170

ABSTRACT:
Ethylene oxide and water are reacted in a reactor and the reaction product is subjected to distillation in a plurality of distillation columns, in the first columns water and components having a boiling point below that of monoethylene glycol and higher ethylene glycols, if any, being distilled off. To obtain extremely pure monoethylene glycol alkali metal compounds are added at a point between the reactor and the monoethylene glycol distillation column in an amount to adjust the pH of the product entering the latter column to a value of from 7 to 10. The monoethylene glycol obtained in this manner is especially pure and has very low UV absorption values. It is, therefore, especially suitable for the manufacture of polyester fibers.

REFERENCES:
patent: 2788373 (1957-04-01), Mills et al.
patent: 2793235 (1957-05-01), Jenkinson
patent: 3408268 (1968-10-01), Pitts et al.
patent: 3875019 (1975-04-01), Cocuzza et al.
patent: 3904656 (1975-09-01), Broz
patent: 3970711 (1976-07-01), Reiche et al.
patent: 4225394 (1980-09-01), Cox et al.

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