Process for the manufacture of carboxylic peracids

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260502A, C07C17910, C07C17912

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active

042671248

ABSTRACT:
A continuous process for the manufacture of carboxylic peracids by reacting the corresponding carboxylic acid with hydrogen peroxide in the presence of a catalyst and in the presence of an inert organic liquid which is a solvent for the peracid and is capable of forming a heterogeneous azeotrope with water, removing the water present in the reaction mixture by distillation of the water/organic liquid azeotrope, and keeping sufficient water in the reaction mixture to allow the formation of an aqueous phase which is separate from an organic phase containing the organic liquid.

REFERENCES:
patent: 2814641 (1957-11-01), Phillips et al.
patent: 3264346 (1966-08-01), Weiberg
patent: 3284491 (1966-11-01), Karach et al.

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