Process for the manufacture of 2,2,4,4-tetramethycyclobutanediol

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568301, 568338, C07C 29145

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active

051699940

ABSTRACT:
Disclosed is a novel process for the manufacture of 2,2,4,4-tetramethylcyclobutanediol commencing with the pyrolysis of isobutyric anhydride to produce dimethylketene. Dimethylketene is absorbed into certain carboxylate ester solvents which function as the process solvents for subsequent dimerization of the dimethylketene to 2,2,4,4-tetramethylcyclobutanedione followed by the catalytic hydrogenation of the dione to the diol product.

REFERENCES:
patent: 2936324 (1960-05-01), Hasek et al.
patent: 3000906 (1961-09-01), Hasek et al.
patent: 3190928 (1965-06-01), Elam et al.
Mugno et al., Chim. Ind. (Milan) 46(1), pp. 5-9 (1964); Chemical Abstracts, 60:9143f.

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