Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1991-08-20
1992-12-08
Reamer, James H.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568301, 568338, C07C 29145
Patent
active
051699940
ABSTRACT:
Disclosed is a novel process for the manufacture of 2,2,4,4-tetramethylcyclobutanediol commencing with the pyrolysis of isobutyric anhydride to produce dimethylketene. Dimethylketene is absorbed into certain carboxylate ester solvents which function as the process solvents for subsequent dimerization of the dimethylketene to 2,2,4,4-tetramethylcyclobutanedione followed by the catalytic hydrogenation of the dione to the diol product.
REFERENCES:
patent: 2936324 (1960-05-01), Hasek et al.
patent: 3000906 (1961-09-01), Hasek et al.
patent: 3190928 (1965-06-01), Elam et al.
Mugno et al., Chim. Ind. (Milan) 46(1), pp. 5-9 (1964); Chemical Abstracts, 60:9143f.
Gustafson Bruce L.
Knight Jennifer R.
Sumner, Jr. Charles E.
Eastman Kodak Company
Heath, Jr. William P.
Reamer James H.
Thomsen J. Frederick
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