Process for the manufacture of 1,2-epoxy-3-chloropropane

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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Reexamination Certificate

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08058459

ABSTRACT:
Process for the manufacture of 1,2-epoxy-3-chloropropane by reaction between allyl chloride and hydrogen peroxide in the presence of a catalyst and in the possible presence of at least one solvent in an epoxidation medium comprising at least one liquid phase, in which process the pH of the liquid phase is controlled and maintained at a value of greater than or equal to 1.5 and less than 4.8.

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Carlo Venturello: “A New, Effective Catalytic System for Epoxidation of Olefins by Hydrogen Peroxide under Phase-Transfer Conditions.” J. Org. Chem., vol. 48, No. 21, pp. 3831-3833, 1983. XP001012726.
Carlo Venturello: “Quaternary Ammonium Tetrakis(diperoxotungsto)phosphates(3-) as a New Class of Catalysts for Efficient Alkene Epoxidation with Hydrogen Peroxide” J. Org. Chem., vol. 53, No. 7, pp. 1553-1557, 1988. XP002235620.

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