Process for the manufacture of 1,1,1,2-tetrafluoro-2-chloroethan

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570166, 570168, C07C 1708

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056168209

ABSTRACT:
The invention relates to a process for the manufacture of 1,1,1,2-tetrafluoro-2-chloroethane and of pentafluoroethane.
The process, which consists of the gas phase catalytic fluorination of at least one pentahaloethane of formula C.sub.2 HX.sub.2-n F.sub.3+n in which X denotes a chlorine or bromine atom and n the number 0 or 1 by means of hydrofluoric acid, is characterized in that there is used a mixed catalyst composed of oxides, halides and/or oxyhalides of nickel and chromium deposited on a support consisting of aluminium fluoride or a mixture of aluminium fluoride and alumina.

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