Process for the isomerization of isolated double bonds to conjug

Details Process for the isomerization of isolated double bonds to conjug Process for the isomerization of isolated double bonds to conjug

1983-01-13

1984-02-28

Gantz, Delbert E.

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

By double-bond shift

585601, 585664, 585665, C07C 530

Patent

active

044343108

ABSTRACT:
A process for the isomerization of isolated double bonds to conjugated double bonds in optionally substituted cyclooctadienes using alkali metal or alkaline earth metal amides, if desired in the presence of a solvent, requires that the alkali metal or alkaline earth metal amide be produced with exclusion of moisture and under a protective gas atmosphere in the presence of the cyclooctadiene to be isomerized; and that the isomerization be conducted at temperatures of 70.degree.-200.degree. C.

REFERENCES:
patent: 3080432 (1963-03-01), Voltz et al.
patent: 3124621 (1964-03-01), Crain et al.
patent: 3309410 (1967-03-01), Schriesheim et al.
patent: 3441629 (1969-04-01), Zuech
patent: 3507928 (1970-04-01), Rinehart
patent: 3767716 (1971-09-01), Tsuneyuki
patent: 3856877 (1974-12-01), Otsuki et al.
patent: 3872178 (1975-03-01), Tabler

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