Process for the isomerization of benzene containing feed streams

Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – With subsequent diverse conversion

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585263, 585266, 585750, 585258, 585734, C07C 522, C07C 113, C07C 510

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059627557

ABSTRACT:
A process for saturating benzene in a light paraffin isomerization process can accommodate varying quantities of benzene through the incorporation of progressive steps that control temperatures in the isomerization zone while performing a majority of the saturation within an immediately upstream benzene saturation zone. The process is suited for saturating benzene to very low levels while feedstream concentrations of benzenes may vary from 2 to 25 wt % throughout a given period of operation. The process can accommodate rapid swings in benzene concentration that may occur on a daily basis. The invention is particularly suited for the use of a sulfated zirconia catalyst that allows the utilization of existing reactor vessels in an isomerization process.

REFERENCES:
patent: 4783575 (1988-11-01), Schmidt et al.
patent: 5003118 (1991-03-01), Low et al.
patent: 5763713 (1998-06-01), Blommel et al.

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