Process for the isolation of noble metals

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Platinum group metal

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423 25, 423 27, 423 34, 423 42, 423 24, 75744, C22B 1104

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active

049254855

ABSTRACT:
The present invention involves the isolation or leaching of noble metals from materials containing noble metals, e.g. ores, by treating the noble metal- containing materials with a cyclic thiourea derivative under acid pH conditions. Removal is effected by adsorption onto charcoal or by an ion exchanger, for example. Preferred cyclic thioureas are N,N'-ethylenethiourea and N,N'-propylenethiourea and the acid pH conditions may be achieved by sulfuric acid or hydrochloric acid solutions containing 0.01 to 2.0% by weight of the cyclic thiourea.

REFERENCES:
patent: 3473921 (1969-11-01), Schmuckler
patent: 4021264 (1977-05-01), Knorre et al.
Groenewald, T., "The Dissolution of Gold in Acidic Solutions of Thiourea", Hydrometallurgy 1, (1976), pp. 277-290.
Hiskey, J. Brent, "Thiourea as a Lifivant for Gold and Silver", Proceedings from the 110th Al Me Meeting, Chicago, Ill., (1981), p. 83.

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