Process for the hydrosulfination of olefins

Details Process for the hydrosulfination of olefins Process for the hydrosulfination of olefins

1994-09-01

1996-04-23

Chan, Nicky

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfinic or sulfenic acids or salts thereof

562120, 560307, 568 31, C07C31304

Patent

active

055105181

ABSTRACT:
Process for the preparation of olefins by using a palladium catalyst at a temperature above the ceiling temperature of the SO.sub.2 /olefin copolymer system, for the synthesis of sulfinic and sulfonic acid derivatives.

REFERENCES:
Journal of Organic Chemistry, vol. 56, No. 19, Sep. 13, 1991, Furguson, et al., "Mercury-photosensitised suphinatio, hydrosulphination, and carbonylation of hydrocarbons: alkane and alkene conversion to sulphinic acid", pp. 5503-5510.
Journal of the Chemical Society, Chemical Communications, Keim et al., 1993, Palladium-catalyzed Hydrosulfination: Synthesis of Sulfonic Acids and S-Alkyl Alkanethiosulfonates from Alkenes, Sulphur Dioxide and Hydrogen.

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