Process for the hydrogenative conversion of heavy oils and resid

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Cracking

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208144, 208180, 208400, 208434, 585240, 585241, C10G 4902

Patent

active

050645234

ABSTRACT:
Process for the hydrogenative conversion of heavy oils and residual oils, used oils and waste oils, mixed with sewage sludge in a typical liquid phase hydrogenator with gases containing hydrogen, with the addition of a finely ground substance that preferably has a large internal surface area, as additive. The additive is added in two different particle size ranges so that a portion of the additive is present as a fine particle size fraction iwth a particle size of 90 .mu.m or less and another portion as a coarse particle size fraction with a particle size of 100 .mu.m to 2000 .mu.m, preferably 100 to 1000 .mu.m with the procedure being carried out with a weight ratio of raw oils to sewage sludge used of 10:1 to 1:1.5. Conversion of vacuum residue of a Venezuelan heavy oil with the addition of 2 wt. % of lignite coke as additive and with the admixture of 10 wt. % industrial or municipal sewage sludge in a liquid phase hydrogenator to obtain useful liquid products in particular, and extensive conversion of the organic fractions of the sewage sludge.

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patent: 4206032 (1980-06-01), Friedman et al.
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patent: 4417976 (1983-11-01), Sander et al.
patent: 4618735 (1986-10-01), Bridle et al.
patent: 4652686 (1987-03-01), Coenan et al.

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