Process for the hydrogenation of olefins and aromatic compounds

Mineral oils: processes and products – Chemical conversion of hydrocarbons – Hydrogenation

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208264, C10G 4554

Patent

active

042409004

ABSTRACT:
Olefins and aromatic compounds in mixed hydrocarbon streams boiling above about 200.degree. F. are hydrogenated at a temperature ranging between about 400.degree. F.-720.degree. F. using a zeolite-containing catalyst that has been treated with a hydrocarbon stream relatively high in organic nitrogen compounds to suppress the cracking activity of the catalyst. The catalyst comprises (1) an amorphous base component, (2) a crystalline aluminosilicate component preferably comprising 5-30 wt. % of the total catalyst and having a silica/alumina mole ratio of at least 2.5 and an alkali metal content of less than about 2.0 wt. %, and (3) a transition metal hydrogenation component. The process is particularly useful in the manufacture of jet fuels and technical white oils and white oil bases with a minimum conversion of feed (<20%) to substantially lower boiling products.

REFERENCES:
patent: 3459656 (1969-08-01), Rausch
patent: 3547807 (1970-12-01), Hansford
patent: 3592757 (1971-07-01), Bard
patent: 3730878 (1973-05-01), Pollitzer
patent: 3779899 (1973-12-01), Mears
patent: 3788972 (1974-01-01), Henry et al.

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