Process for the hydriding of halogen-substituted compounds

Details Process for the hydriding of halogen-substituted compounds Process for the hydriding of halogen-substituted compounds

1990-08-10

1992-06-30

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556 7, 556 8, 556 9, 556 13, 556 64, 556 81, 556 70, 556 87, 556 95, 556104, 556487, 556489, 568 1, 568 16, 568 17, C07F 702, C07F 502, C07F 902

Patent

active

051264730

ABSTRACT:
A process is described for the hydrided of halogen-substituted compounds of the second to fourth period of Groups III to V of the periodic system, with the exception of gallium, aluminum, carbon, or nitrogen. A finely-granulated aluminum is added to a molten salt melt that consists of 50-67 molar % AlCl.sub.3 (anhydrous) and 50 to 33 molar % of sodium chloride. Then to the stirred, or by some other means dispersed suspension, hydrogen is introduced to hydrided the finely-dispersed aluminum. Thereafter the mixture is reacted with the halogen-substituted compound and the resulting hydrided compound is renewed.

REFERENCES:
Grant, J., Hackh's Chemical Dictionary, 4th Ed., McGraw-Hill Book Co., N.Y., pp. 329-330, 1972.
Inorganic Chemistry, vol. II, pp. 43-46, (1963).
Z. Chem. vol. 23, 1983, p. 349.
Agnew. Chem., vol. 70, 1958, p. 625-627.

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