Process for the generation of pure hydrogen for use with fuel ce

Gas: heating and illuminating – Processes – Hydrogen

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48 76, 481277, 481279, 481987, 252373, 252376, 422177, 429 17, 429 20, C10K 304

Patent

active

061622672

ABSTRACT:
A process and apparatus are disclosed for the operation of a fuel cell to generate electric power from a feed stream comprising a hydrocarbon or an alcohol. The fuel cell comprises a proton exchange membrane which produces electric power from a hydrogen product stream which comprises essentially no carbon monoxide. The hydrogen product stream is produced from the feed stream in a novel steam reforming zone containing a steam reforming catalyst disposed in a bell-shaped catalyst zone. The bell-shaped catalyst zone is disposed over a combustion zone such that the exhaust gas from the combustion flows around the bell-shaped catalyst zone to heat the catalyst from the inside and the outside of the catalyst zone. Furthermore, the bell-shaped catalyst zone maintains a high inlet and a high outlet temperature to avoid methane slippage in the steam reforming zone. Heat for the steam reforming zone is provided by a fuel stream and at least a portion of the anode waste gas stream from the fuel cell.

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Wnek, Gary E.; Rider, Jeffrey N.; Serpico, Joseph M.; Einset, Alison G., Ehrenberg, Scott G.; and Raboin, Louis A., "New Hydrocarbon Proton Exchange Membranes Based On Sulfonated Styrene-Ethylene/Butylene-Styrene Triblock Copolymers," Electrochemical Society Proceedings, Vol. 95-23, pp. 247-251.

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