Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1991-12-09
1994-04-05
Dees, Jose G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5116
Patent
active
053006844
ABSTRACT:
Disclosed is a process for oxidizing ethane to acetic acid which comprises feeding ethane and a recycle gas to a fluidized bed reaction zone containing fluidized particulate solid oxidation catalyst, feeding a molecular oxygen-containing gas separately from said ethane to said reaction zone so that said molecular oxygen-containing gas first mixes with the major portion of the combustible hydrocarbon feed gases within the fluidized bed, said process including the steps of (1) cooling the gaseous effluent from the reaction zone, (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxides contained in said effluent, (3) purging a small portion of said gaseous stream and recycling most of said gaseous stream as part of the feed to said reaction zone,
REFERENCES:
patent: 3948983 (1976-04-01), Hackmann et al.
patent: 5162578 (1992-11-01), McCain et al.
Reactions of Pure Hydrocarbons, Egloff, (ACS Monograph Series #73) (1937) pp. 99-111 and 146.
Solomon's, Organic Chemistry, 2nd Ed., p. 266.
Benkalowycz Nancy C.
Blum Patricia R.
Wagner David R.
Conrad, III Joseph M.
Dees Jos,e G.
Esposito Michael F.
Lynch Charles S.
The Standard Oil Company
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