Process for the epoxidation of olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

10724300

ABSTRACT:
A process for the catalytic epoxidation of olefins in the presence of a titanium containing zeolite catalyst and a polar solvent whereby the deactivation of the catalyst upon recycling of the solvent has been considerably reduced. In the process one or more nitrogen containing compounds are introduced at some stage, a solvent stream is recovered, treated to contain less than 50 wppm nitrogen in the form of organic nitrogen compounds and at least a part of it is recycled to the epoxidation step. Also disclosed is a process for the catalytic epoxidation of propene which integrates the treatment and recycle of the solvent into the workup of the reaction mixture.

REFERENCES:
patent: 2870171 (1959-01-01), Gable
patent: 4410501 (1983-10-01), Taramasso et al.
patent: 4833260 (1989-05-01), Neri et al.
patent: 4999179 (1991-03-01), Sugihara et al.
patent: 5523426 (1996-06-01), Jubin, Jr. et al.
patent: 5591875 (1997-01-01), Chang et al.
patent: 5599955 (1997-02-01), Vora et al.
patent: 5620935 (1997-04-01), Thiele
patent: 5675026 (1997-10-01), Thiele
patent: 5760253 (1998-06-01), Danner et al.
patent: 5849937 (1998-12-01), Jubin, Jr. et al.
patent: 5849938 (1998-12-01), Rueter et al.
patent: 5912367 (1999-06-01), Chang
patent: 6042807 (2000-03-01), Faraj
patent: 6063941 (2000-05-01), Gilbeau
patent: 6372924 (2002-04-01), Thiele
patent: 6429322 (2002-08-01), Catinat et al.
patent: 196 23 611 (1997-12-01), None
patent: 197 23 950 (1998-12-01), None
patent: 197 54 185 (1999-02-01), None
patent: 198 35 907 (2000-02-01), None
patent: 199 36 547 (2001-02-01), None
patent: 100 26 363 (2001-11-01), None
patent: 0 100 118 (1984-02-01), None
patent: 0 100 119 (1984-02-01), None
patent: 0 133 510 (1985-02-01), None
patent: 0 230 349 (1987-07-01), None
patent: 0 230 949 (1987-08-01), None
patent: 0 425 893 (1991-05-01), None
patent: 0 568 336 (1993-11-01), None
patent: 0 568 337 (1993-11-01), None
patent: 0 583 828 (1994-02-01), None
patent: 0 645 473 (1995-03-01), None
patent: 0 659 473 (1995-06-01), None
patent: 0 712 852 (1996-05-01), None
patent: 0 719 768 (1996-07-01), None
patent: 0 757 043 (1997-02-01), None
patent: 0 757 045 (1997-02-01), None
patent: 0 795 537 (1997-09-01), None
patent: 0 827 765 (1998-03-01), None
patent: 0 930 308 (1999-07-01), None
patent: 0 936 219 (1999-08-01), None
patent: 0 940 393 (1999-09-01), None
patent: 1 072 599 (2001-01-01), None
patent: 1 072 600 (2001-01-01), None
patent: 1 122 248 (2001-08-01), None
patent: 1 138 387 (2001-10-01), None
patent: 1 167 290 (2002-07-01), None
patent: 1 221 442 (2002-07-01), None
patent: 2 810 981 (2002-01-01), None
patent: 2166636 (1990-06-01), None
patent: WO 97/47613 (1997-12-01), None
patent: WO 97/47614 (1997-12-01), None
patent: WO 98/47645 (1998-10-01), None
patent: WO 99/01445 (1999-01-01), None
patent: WO 99/07690 (1999-02-01), None
patent: WO 99/08985 (1999-02-01), None
patent: WO 99/11639 (1999-03-01), None
patent: WO 99/14208 (1999-03-01), None
patent: WO 99/23052 (1999-05-01), None
patent: WO 00/07695 (2000-02-01), None
patent: WO 00/17178 (2000-03-01), None
patent: WO 00/25881 (2000-05-01), None
patent: WO/76989 (2000-12-01), None
patent: WO 01/57009 (2001-08-01), None
patent: WO 01/57010 (2001-08-01), None
patent: WO 01/57012 (2001-08-01), None
patent: WO 01/68623 (2001-09-01), None
patent: WO 01/92242 (2001-12-01), None
patent: WO 02/00634 (2002-01-01), None
patent: WO 02/00635 (2002-01-01), None
patent: WO 02/02544 (2002-01-01), None
patent: WO 02/02545 (2002-01-01), None
patent: WO 02/14298 (2002-02-01), None
patent: WO 02/14299 (2002-02-01), None
Haas, T. et al ‘Process for the expxidation of olefins with hydrogen peroxide in the presence of titanium zeolites’ CA 141:7630 (2004).
Paparatto, G. et al ‘Integrated process for the preparation of olefin oxides’ CA 136:184272 (2002).
Ponceau, M. et al ‘Production of epoxides by epoxidation of olefins with regeneration of catalyst’ CA 134:147992 (2001).
Goor, G. et al., “Ullmann's Encyclopedia of Industrial Chemistry, Fifth Edition,” 1989, pp. 447-457, vol. A 13, XP-002233848, VCH Verlasgesellschaft, Weinheim, Germany (11 pages).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for the epoxidation of olefins does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for the epoxidation of olefins, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for the epoxidation of olefins will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3782064

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.