Process for the enzymatic cleavage of vinyl 2-aryl-propionates

Details Process for the enzymatic cleavage of vinyl 2-aryl-propionates Process for the enzymatic cleavage of vinyl 2-aryl-propionates

1990-06-08

1992-10-13

Lilling, Herbert J.

Chemistry: molecular biology and microbiology

Micro-organism, tissue cell culture or enzyme using process...

Preparing heterocyclic carbon compound having only o, n, s,...

435 42, 435121, 435123, 435126, 435132, 435135, 435136, 435147, 435197, 435280, C12P 4100, C12P 740, C12N 914, C12N 954

Patent

active

051550288

ABSTRACT:
In the enzymatic stereoselective ester cleavages of 2-arylpropionate, the reaction rate of the hydrolyzing enzymes can be drastically increased if the vinyl ester of the 2-arylpropionate is employed as the substrate.

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patent: 4963492 (1990-10-01), Keller et al.
M. Degueil-Castaing et al., Enzymatic Reactions In Organic Synthesis: 2-Ester Interchange of Vinyl Esters, Tet. Letters, V.28,N.9, pp. 953-954, 1987.
J. W. Young et al., Membrane Reactors For The Biocatalytic Production Of Chiral Compounds, Chiral 90 (1990) pp. 23-28.
Klaus Mosbach, Methods in Enzymology, vol. XLIV, Academic Press, (1976) pp. 263-267; 551-556.
Iriuchijima et al. "Asymmetric Hydrolysis of (.+-.)--alpha-Substituted Carboxylic Acid Esters with Microorganisms" Agric. Biol. Chem. 45 (6), pp. 1389-1392 (1981).

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