Process for the enantioselective production of .alpha.-vinyl-.al

Details Process for the enantioselective production of .alpha.-vinyl-.al Process for the enantioselective production of .alpha.-vinyl-.al

1986-10-08

1988-05-17

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

548301, 562443, 562445, 562449, C07C10104

Patent

active

047452188

ABSTRACT:
.alpha.-Vinyl-.alpha.-aminocarboxylic acids of the general formula: ##STR1## where * indicates a center of asymmetry and R is hydrogen, deuterium, lower alkyl, allyl, benzyl, or benzyl substituted 1 to 3 times by alkyl, alkoxy, fluorine or chlorine and produced enantioselectively from L-methionine by a multistep process.

REFERENCES:
patent: 3960927 (1976-06-01), Metcalf
patent: 4585892 (1986-04-01), Seebach

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