Process for the electrochemical synthesis of organosilicon compo

Details Process for the electrochemical synthesis of organosilicon compo Process for the electrochemical synthesis of organosilicon compo

1994-06-16

1996-07-23

Niebling, John

Electrolysis: processes, compositions used therein, and methods

Electrolytic synthesis

Preparing organic compound

204257, 204265, 204277, 204208, 204290R, 204294, C25B 300

Patent

active

055386180

ABSTRACT:
A process is described for the electrochemical preparation of organosilicon compounds having at least one SiC-bound organic radical, a solution which contains at least one halosilane being subjected to an electrochemical reaction, an anode which contains a noble metal or an alloy consisting essentially of one or more noble metals having a halogen scavenger flowing around said anode.

REFERENCES:
patent: 3103473 (1963-09-01), Juda
patent: 4292434 (1981-09-01), Lindner et al.
patent: 4695441 (1987-09-01), Lahoda et al.
"Electrosynthese en chimie organosilicique: Preparation de phenyl-et benzyl-trimethylsilanes", P. Pons et al., J. of Org. Chem., 321 (no month 1987) C27-C29.
"Electrosynthese en chimie organosilicique: Silylation selective de polychloromethanes", P. Pons et al., of Org. Chem., 358(no month 1988) 31-37.
Electrochimica Acta, Bd. 35, No. 11, (no month 1990), Oxford, UK, pp. 1867-1872 "Electroreductive Polymerisation of Organodichl oromonosilanes" by Umezawa et al.

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