Process for the electrochemical synthesis of organic metal compo

Details Process for the electrochemical synthesis of organic metal compo Process for the electrochemical synthesis of organic metal compo

1973-10-03

1976-06-22

Andrews, R. L.

Chemistry: electrical and wave energy

Processes and products

204 59QM, 204 78, 204 79, B01K 300

Patent

active

039649830

ABSTRACT:
Process for reacting an H-acidic organic compound, in which the acidic H-atom is bonded to the organic radical by an oxygen or a sulphur atom, e.g. an alcohol, with a metal having a standard potential which is more positive than -1.66 volts and which at most reacts with the H-acidic compound under current-free conditions, e.g. Ni, Co, Fe, Mn, Sb, Cu, or Au. The H-acidic compound or a solution thereof is a polar solvent is made conducting by addition of a soluble salt of chlorine, bromine or iodine, and is electrolysed at a temperature of up to 150.degree.C, using said metal as the anode, for production of the alcoholate.

REFERENCES:
patent: 2438963 (1948-04-01), Cunningham et al.
patent: 3730857 (1973-05-01), Tripp

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