Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1995-05-05
1996-08-13
Pal, Asok
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585510, 585514, 585531, 585527, 585528, 585369, 585361, C07C 252, C07C 220
Patent
active
055457894
ABSTRACT:
The invention relates to a process for the dimerization of a conjugated diene using an iron triad metal nitrosyl halide, in combination with a reducing agent, as catalyst. The process is characterized in that the dimerization is carried out in the presence of nitrogen monoxide (NO). The invention is of interest in particular for the dimerization of butadiene to 4-vinyl cyclohexene.
REFERENCES:
patent: 3655793 (1972-04-01), Myers
patent: 4144278 (1979-03-01), Strope
patent: 4181707 (1980-01-01), Strope
Duisters Henricus A. M.
Haenen Johan G.D.
DSM N.V.
Pal Asok
Yildirim Bekir L.
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