Process for the dimerization of a conjugated diene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585510, 585514, 585531, 585527, 585528, 585369, 585361, C07C 252, C07C 220

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055457894

ABSTRACT:
The invention relates to a process for the dimerization of a conjugated diene using an iron triad metal nitrosyl halide, in combination with a reducing agent, as catalyst. The process is characterized in that the dimerization is carried out in the presence of nitrogen monoxide (NO). The invention is of interest in particular for the dimerization of butadiene to 4-vinyl cyclohexene.

REFERENCES:
patent: 3655793 (1972-04-01), Myers
patent: 4144278 (1979-03-01), Strope
patent: 4181707 (1980-01-01), Strope

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