Process for the detoxification of cyanide-containing aqueous sol

Liquid purification or separation – Processes – Including controlling process in response to a sensed condition

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210759, 210763, 210904, C02F 172

Patent

active

052079252

ABSTRACT:
A process is disclosed for the detoxification of aqueous solutions containing cyanides and/or cyano complexes in the presence of heavy metals which are Mn, Co, Ni, Cu, Cd and Zn, more particularly Cu, by oxidative treatment of the solutions with peroxide compounds at pH values of 8 to 12. Peroxide compounds from the group consisting of alkali metal percarbonates and alkaline earth metal peroxides are used. The peroxide compounds are added to the solutions to be detoxified per se or are formed in situ therein from hydrogen peroxide and other components. Sodium perborate, sodium percarbonate and calcium peroxide are preferred.

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Gmelin Handbook of Inorganic Chemistry, 8th Edition, 3rd Supplement, 8th Edition, vol. 2, 1987, pp. 177-179 European Search Report.

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