Process for the destruction of by-product tetranitromethane

Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing

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423236, 568944, 568948, 149124, C01B 2146, C01B 2138

Patent

active

047132329

ABSTRACT:
A process for the management of by-product tetranitromethane (TNM) which avoids the hazards of the prior art isolation or extraction procedures. A selected in-plant liquid or vapor stream, or a reactor off-gas stream from nitration or nitric acid oxidation plant, which contains TNM, is heated to effectively pyrolyze the TNM without undue losses of nitric acid values.

REFERENCES:
patent: 1632959 (1927-06-01), Gartner
patent: 3781374 (1973-12-01), Fossan
patent: 4001373 (1977-01-01), Hall et al.
patent: 4003977 (1977-01-01), Gilligan et al.
Urbanski, T., Chemistry and Technology of Explosives, vol. I, MacMillan Co., N.Y., 1964, pp. 588-594.

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