Process for the destruction of alkylphosphate

Compositions – Radioactive compositions – Nuclear reactor fuel

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210759, 210763, G21F 908, C02F 172

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active

051146231

ABSTRACT:
Alkyl phosphates, which may be dissolved in a hydrocarbon solvent can be destroyed in a two-stage process, the first stage involving hydrolysis with concentrated alkali to effect partial de-alkylation of the alkyl phosphate the second stage involving catalytic oxidation of the de-alkylated phosphate with hydrogen peroxide. This results in improved safety as oxidation takes place after much of the hydrocarbon has been removed at the first stage.

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patent: 4377508 (1983-03-01), Rothberg
patent: 4394269 (1983-07-01), Tallent et al.
patent: 4624792 (1986-11-01), Yamanaka
patent: 4950425 (1990-08-01), Rowbottom et al.
Japanese Patent Gazette, week 8729, Sep. 2, 1987, Accession No. 87202132/29, Derwent Publications Ltd., London, GB; & JP-A-62129799 (Toshiba K.K.) Dec. 6, 1987.
Japanese Patent Gazette, week A38, Nov. 1, 1978, accession No. 67964A/38 Derwent Publications Ltd., London, GB; & JP-A-53 094 445 (Tokyo Org. Chem. Ind. K.K.) Aug. 18, 1978.

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