Process for the dehydrocyclization of aliphatic hydrocarbons

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585419, 585444, 585445, 208137, C10G 3506, C07C 252

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active

047958464

ABSTRACT:
An improved dehydrocyclization process for the selective conversion of light hydrocarbons to aromatics is presented. The activity of a catalyst containing nonacidic L-zeolite is greatly enhanced by the addition of water, water precursors, or mixtures thereof to the reaction zone during the dehydrocyclization reaction. Addition of between 10 and 100 wt. ppm H.sub.2 O results in a higher product yield of aromatics with increased product octane.

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