Process for the dehalogenation of 1,3-dioxolanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D31742

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active

052450546

ABSTRACT:
A process for the dehalogenation of 1,3-dioxolanes of formula: ##STR1## wherein X.sub.1 and X.sub.3, like or different from each other, are Cl or Br, X.sub.2 and X.sub.4, like or different from each other, are F or H. Said process consists in contacting the dioxolane of formula (I) with metallic zinc at a temperature ranging from +30.degree. to 130.degree. C. The corresponding dioxoles are obtained.

REFERENCES:
patent: 3865845 (1975-02-01), Resnick
patent: 4393227 (1983-07-01), Squire
patent: 4485250 (1982-09-01), Squire
patent: 4496750 (1985-01-01), Anderson et al.
patent: 4533741 (1985-08-01), Squire
patent: 4535175 (1985-08-01), Squire
patent: 4908461 (1990-03-01), Hung

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