Process for the conversion of ethylene into but-1-ene using addi

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585510, 585511, 585520, 585521, 585522, 585523, 585524, C07C 226

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active

057928959

ABSTRACT:
The invention concerns an improved process for the conversion of ethylene into but-1-ene, wherein the ethylene is brought into contact with a catalyst obtained by the interaction of an alkyl titanate, possibly mixed with an ether, with a compound of aluminium of the formula AlR.sub.3 or AlR.sub.2 H, and in the presence of an additive formed by at least one polyethylene glycol and/or one of its derivatives such as a monoether or a monoester of polyethylene glycol.

REFERENCES:
patent: 3879485 (1975-04-01), Belov et al.
patent: 4532370 (1985-07-01), Le Quan et al.
patent: 4615998 (1986-10-01), Le Quan et al.

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