Process for the conversion of an alkane to a mixture of an alcoh

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568385, 568836, 568910, C07C 4527

Patent

active

044594275

ABSTRACT:
A mixture of the alcohol and ketone derivatives of alkanes is produced by reacting the alkane with a hydrocarbyl hydroperoxide, eg t-butyl hydroperoxide, at ambient or elevated temperature and pressure in the presence as catalyst of an iron or manganese square planar complex having heterocyclic nitrogen-donor ligands, e.g. a porphyrin or phthalocyanine complex, which complex has either no axial ligands, eg the lower valency or cationic complex, or an axial ligand which is non-coordinating or weakly-coordinating.

REFERENCES:
patent: 3879467 (1975-04-01), Zajacek et al.

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