Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1982-10-26
1984-07-10
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568385, 568836, 568910, C07C 4527
Patent
active
044594275
ABSTRACT:
A mixture of the alcohol and ketone derivatives of alkanes is produced by reacting the alkane with a hydrocarbyl hydroperoxide, eg t-butyl hydroperoxide, at ambient or elevated temperature and pressure in the presence as catalyst of an iron or manganese square planar complex having heterocyclic nitrogen-donor ligands, e.g. a porphyrin or phthalocyanine complex, which complex has either no axial ligands, eg the lower valency or cationic complex, or an axial ligand which is non-coordinating or weakly-coordinating.
REFERENCES:
patent: 3879467 (1975-04-01), Zajacek et al.
Middleton Anthony R.
Smith David J. H.
Lone Werren B.
The British Petroleum Company p.l.c.
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