Process for the conversion of a terminal carbon-carbon double bo

Details Process for the conversion of a terminal carbon-carbon double bo Process for the conversion of a terminal carbon-carbon double bo

1983-09-28

1986-02-04

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568360, C07C 4534

Patent

active

045687706

ABSTRACT:
Terminal carbon-carbon double bonds of olefinic hydrocarbons are converted to carbonyl groups by reacting the olefin with oxygen in the presence of (a) a catalyst comprising (i) one or more of the metals palladium, rhodium, ruthenium or iridium, and (ii) copper, (b) a diluent comprising two liquid phases, and (c) a surfactant, provided that when the metal is palladium no alkali or alkaline earth metal is present and the surfactant is dodecyltrimethylammonium or cetyltrimethylammonium chloride or bromide.

REFERENCES:
patent: 3131223 (1964-04-01), Smidt et al.
patent: 3154586 (1964-10-01), Bander et al.
patent: 4152354 (1979-05-01), Stapp
patent: 4203927 (1980-05-01), Stapp
patent: 4220604 (1980-09-01), Stapp
patent: 4271320 (1981-06-01), Tokitoh et al.
patent: 4419525 (1983-12-01), Shioyama et al.
patent: 4434082 (1984-02-01), Nurtha et al.

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