Process for the condensation of carbonyl and aromatic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568728, 585446, C07C 3916

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active

047773014

ABSTRACT:
An aldehyde or ketone is condensed with an aromatic compound by contacting the aldehyde or ketone and the aromatic compound with a non-zeolitic molecular sieve, which has in its calcined form an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20.degree. C. Among the condensations which can be effected is the condensation of acetone with phenol to produce bisphenol A.

REFERENCES:
patent: 3496239 (1970-02-01), Hamilton et al.
patent: 3728408 (1973-04-01), Tobias
patent: 4011278 (1977-03-01), Plank
patent: 4306106 (1981-12-01), Karr
"Adsorptive Properties of Aluminophosphate Molecular Sieves", G. Dworezkov, et al., in "Adsorption and Catalysis on Oxide Surfaces", M. Che and G. C. Bond, 1985 Elsevier Science Publishers, B.V., Amsterdam, pp. 163 to 172.
Chemical Week, Jun. 25, 1985, p. 52.

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