Process for the co-production of ketones and mono-olefins

Details Process for the co-production of ketones and mono-olefins Process for the co-production of ketones and mono-olefins

1982-07-02

1983-12-20

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568406, 568361, 585275, C07C 4500

Patent

active

044219334

ABSTRACT:
Process for the co-production of ketones and mono-olefins from secondary alcohols and conjugated di-olefins in which dehydrogenation of the secondary alcohol and hydrogenation of the conjugated di-olefin are effected by contacting a mixture of the secondary alcohol and the conjugated di-olefin with a heterogeneous copper-containing catalytic system. The process is very useful for the co-production of methyl ethyl ketone and n-butenes from sec-butanol and butadiene at low temperatures (e.g. between 90.degree. C. and 130.degree. C.).

REFERENCES:
patent: 2066496 (1937-01-01), Taylor
patent: 2794053 (1957-05-01), Altreuter et al.

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