Process for the co-production of aromatic carboxylate and alkyl

Details Process for the co-production of aromatic carboxylate and alkyl Process for the co-production of aromatic carboxylate and alkyl

1987-11-02

1988-10-18

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560 97, 560100, 560102, 560103, 570181, C07C 6736, C07C 1700

Patent

active

047789182

ABSTRACT:
Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an ether and a rhodium catalyst.

REFERENCES:
patent: 2565462 (1951-08-01), Prichard et al.
patent: 3988358 (1976-10-01), Heck
Nakayama and Mizoroki, Bull. Chem. Soc. Japan, 42, No. 4, (Apr. 1969), 1124-1129.
Alper et al., Angew. Chem. Int. Ed. Engl., 23, Sep. (1984), No. 9, 732-733.
T. Hudlicky et al., The Chemistry of Halides, Pseudohalides and Azides, Supplement D, Part 2, 1142-1158, Dec. 1983.
J. Chem. Soc., 150-153, Dec. (1952).

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