Process for the co-production of aromatic carboxylate and alkyl

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 97, 560100, 560102, 560103, 570181, C07C 6736, C07C 1700

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047789174

ABSTRACT:
Disclosed is a process for the co-production of aromatic carboxylic esters and alkyl iodides by the carbonylation of aromatic iodides in the presence of an ether and a ruthunium catalyst.

REFERENCES:
patent: 2565462 (1951-08-01), Prichard et al.
patent: 3988358 (1976-10-01), Heck
Nakayama and Mizoroki, Bull. Chem. Soc. Japan 42 No. 4, (Apr. 1969), 1124-1129.
T. Hudlicky et al. The Chemistry of Halides, Pseudohalides and Azides, Supplement D, Part 2, 1142-1158, Dec. 1983.
J. Chem. Soc., 150-153 etc. (1952).

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