Process for the co-oligomerisation of ethylene and alpha...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S171000, C526S172000, C526S348000, C526S348600, C585S527000, C585S531000

Reexamination Certificate

active

07037988

ABSTRACT:
A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXacomplexes and/or one or more [bis-aryliminepyridine MYp.Lb+][NC−]qcomplexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.

REFERENCES:
patent: 5955555 (1999-09-01), Bennett
patent: 6407188 (2002-06-01), Guan et al.
patent: 6414098 (2002-07-01), Engehausen et al.
patent: 6417305 (2002-07-01), Bennett
patent: 6417364 (2002-07-01), Lenges
patent: 6441117 (2002-08-01), Cameron
patent: 6451939 (2002-09-01), Britovsek et al.
patent: 6455660 (2002-09-01), Clutton et al.
patent: 6458739 (2002-10-01), Kimberley et al.
patent: 6458905 (2002-10-01), Schmidt et al.
patent: 6461994 (2002-10-01), Gibson et al.
patent: 6462152 (2002-10-01), Berardi et al.
patent: 6462155 (2002-10-01), Okuda
patent: 6465386 (2002-10-01), Maddox et al.
patent: 6472341 (2002-10-01), Kimberley et al.
patent: 6479601 (2002-11-01), Kerns et al.
patent: 6683187 (2004-01-01), De Boer et al.
patent: 6710006 (2004-03-01), De Boer et al.
patent: 6825297 (2004-11-01), Devore et al.
patent: 2002/0028941 (2002-03-01), De Boer et al.
patent: 1125928 (2001-08-01), None
patent: 1 125 987 (2001-08-01), None
patent: WO 99/02472 (1999-01-01), None
patent: WO 99/51550 (1999-01-01), None
patent: WO 99/12981 (1999-03-01), None
patent: 99/62967 (1999-12-01), None
patent: WO 00/50470 (2000-08-01), None
patent: WO 01/36379 (2001-05-01), None
patent: WO 2/28805 (2002-04-01), None
“Metal-Ion-Directed Synthesis of Homo- and Heteronuclear Dimetallic Schiff Base Podates,” by W. Radecka-Paryzek, M.T. Kaczmarek, and E. Luks,Polish J. Chem.,75, (2001) pp. 35-42.
“1,1′-Diisocyanoferrocene and a Convenient Synthesis of Ferrocenylamine,” by Daan van Leusen and Bart Hessen,Organometallics,2001, pp. 224-226.
U.S. Appl. No. 09/775,128, filed Feb. 01, 2001, DeBoer et al.
“Oligomerisation of Ethylene to Higher βOlefins in Applied Homogeneous Catalysis With Organometallic Compounds,” by D. Vogt, Ed. B. Cornilis, W. A. Herrmann, vol. 1, Ch. 2.3.1.3, VCH (1996) pp. 245-258.
“Iron-Bsed Catalysts With Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear β-Olefins,” B. L. Small and M. Brookhard disclosed inJ. Am. Chem. Soc. 1998, 120, pp. 7143-7144.
“Oligomerisation of Ethylene by Bis(Imino)Pyridyliron and—Cobalt Complexes,” by G. J. P. Britovsek, S. Mastroianni, G. A. Solan, S. P. D. Baugh, C. Redshaw, V. C. Gibson, A. J. P. White, D. J. Williams, and M. R. J. Elsegood, as disclosed inChem. Eur. J. 2000, pp. 2221-2231.
Olefin Polymerization with [{bis(imino)pyridyl}CO11Cl2]: Generation of the Active Species Involves CO1**, by T. Martijn Kooistra et al., Angewandte Chemie. International Edition, WILEY-VCH, Weinheim, DE, vol. 40, No. 24, Dec. 17, 2001, pp. 4719-4722.
“The Nature of the Active Species in Bis(imino)pyridyl Cobalt Ethylene Polymerisation Catalysts,” by Vernon C. Gibson, et al., Chemical Communications-Chemcom, Royal Society of Chemistry, GB, No. 21, 2001, pp. 2252-2253.
“Late Metal Catalysts for Ethylene Homo- and Copolymerization,” by Steven D. Ittel et al., Chemical Reviews, American Chemical Society, Easton, US, vol. 100, No. 4, 2000, pp. 1169-1203.
“Novel Olefin Polymerization Catalysts Based on Iron and Cobalt,” by George J. P. Britovsek et al., Chemical Communications-Chemcom, Roayl Society of Chemistry, GB, No. 7, 1998, pp. 849-850.

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