Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-08-01
1977-05-17
Horwitz, D.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
252429R, C07C 2506, C07C 2508
Patent
active
040241980
ABSTRACT:
In the process for the nuclear chlorination of alkylbenzenes, such as toluene, in the presence of a para-directing catalyst system comprising a substantially iron-free Lewis acid catalyst and thianthrene compound co-catalyst, wherein the reaction mixture is in contact with iron or an alloy thereof, the para-directing effect of the catalyst system is improved by the addition of an amide.
REFERENCES:
patent: 1741305 (1929-12-01), Jaeger
patent: 1946040 (1934-02-01), Stoesser et al.
patent: 3226447 (1965-12-01), Bing et al.
Bose Arun C.
Buckholtz Harry E.
Casella Peter F.
Cookfair Arthur S.
Crossetta, Jr. William J.
Hooker Chemicals & Plastics Corporation
Horwitz D.
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