Process for the chlorination of toluene

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252429R, C07C 2506, C07C 2508

Patent

active

040241980

ABSTRACT:
In the process for the nuclear chlorination of alkylbenzenes, such as toluene, in the presence of a para-directing catalyst system comprising a substantially iron-free Lewis acid catalyst and thianthrene compound co-catalyst, wherein the reaction mixture is in contact with iron or an alloy thereof, the para-directing effect of the catalyst system is improved by the addition of an amide.

REFERENCES:
patent: 1741305 (1929-12-01), Jaeger
patent: 1946040 (1934-02-01), Stoesser et al.
patent: 3226447 (1965-12-01), Bing et al.

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