Process for the chlorination of ethane

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570224, 570244, 570261, C07C 1710, C07C 17158

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active

050970836

ABSTRACT:
A process is provided for the chlorination of ethane using hydrogen chloride, chlorine or mixtures as the chlorinating agent. The process includes reaction steps operated in tandem in separate zones first comprising the reaction of perchloroethylene with hydrogen chloride and oxygen in the presence of an oxychlorination catalyst to give hexachloroethane and water, and second comprising the vapor phase reaction of hexachloroethane with ethane feedstock to produce chlorinated ethanes, chlorinated ethylenes, and hydrogen chloride.

REFERENCES:
patent: 2447410 (1948-08-01), Hampel
patent: 2547139 (1951-04-01), Randall
patent: 3420901 (1969-01-01), Schulz
patent: 3642918 (1972-02-01), Bohl et al.
patent: 4192822 (1980-03-01), Sweeney et al.
patent: 4899000 (1990-02-01), Stauffer
patent: 4990696 (1991-02-01), Stauffer
Stauffer, application Ser. No. 07/297,298.

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