Process for the catalytic synthesis of biaryls and polymers...

Details Process for the catalytic synthesis of biaryls and polymers... Process for the catalytic synthesis of biaryls and polymers...

2005-03-15

2005-03-15

Price, Elvis O. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C556S007000, C556S009000, C556S012000, C556S011000, C556S013000, C556S126000, C556S182000, C556S402000, C540S302000, C526S126000, C502S007000, C585S422000, C562S007000

Reexamination Certificate

active

06867302

ABSTRACT:
A process for producing organic substituted aromatic or heteroaromatic compounds including biaryl and biheteroaryl compounds in a two-step reaction. In the first step, the aromatic or heteroaromatic compound is borylated in a reaction comprising a borane or diborane reagent (any boron reagent where the boron reagent contains a B—H, B—B or B—Si bond) and an iridium or rhodium catalytic complex. In the second step, a metal catalyst catalyzes the formation of the organic substituted aromatic or heteroaromatic compound from the borylated compound and an electrophile such as an aryl or organic halide, triflate (OSO2CF3), or nonaflate (OSO2C4F9). The steps in the process can be performed in a single reaction vessel or in separate reaction vessels. The present invention also provides a process for synthesis of complex polyphenylenes starting from halogenated aromatic compounds.

REFERENCES:
patent: WO 0164688 (2003-09-01), None
Miyaura et al., Synth. Commun. 11: 1981, pp. 513-519.

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