Process for the carboxylation of alcohols in heterogeneous phase

Details Process for the carboxylation of alcohols in heterogeneous phase Process for the carboxylation of alcohols in heterogeneous phase

1974-07-25

1976-09-14

Brust, Joseph P.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07C 6996

Patent

active

039806901

ABSTRACT:
An alcohol is carboxylated into the corresponding carbonate by reacting the alcohol with oxygen and carbon dioxide in the presence of a catalyst system in the heterogeneous phase by introducing the reactants into a reactor charged with a catalyst, such as the complex system formed by copper and 4-vinylpyridine, causing the reactants to flow over the catalyst, and then withdrawing the products of the reaction and unconsumed reactants from the reactor.

REFERENCES:
patent: 3114762 (1963-12-01), Mador et al.
patent: 3227740 (1966-01-01), Fenton
patent: 3227741 (1966-01-01), Fenton
patent: 3445497 (1969-05-01), Anderson et al.
patent: 3625995 (1971-12-01), Brattesani
patent: 3846468 (1974-11-01), Perrotti et al.

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