Process for the biocatalytic coupling of aromatic compounds in t

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process... – Preparing nitrogen-containing organic compound

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435129, 435130, 435136, 435147, 435155, 435156, 435192, 527200, 528 86, 528210, 528212, C12P 722

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active

055410910

ABSTRACT:
A process is described for the dimerization of a substituted aromatic compound of the formula (I): ##STR1## wherein X represents --OH, --SH or --NHR where R is H, an alkyl group or an aryl group; R.sup.1 and R.sup.2 represent an alkyl group, an aryl group, an alkenyl group, an alkynyl group, an alicyclic group, a halogen atom, an alkoxy group, an aryloxy group, a hydroxy group, or an amino group; and R.sup.3 and R.sup.4 can have the same definition as R.sup.1 and R.sup.2 and may additionally represent a hydrogen atom; which comprises reacting the substituted aromatic compound in the presence of a peroxidase enzyme, a peroxide and a radical transfer agent in an aqueous medium.

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patent: 5188953 (1993-02-01), Johnson et al.
Klibanov et al. "Enzymatic Removal of Toxic Phenols and Analines from Waste Water" J. Applied Biochem. 2, pp. 414-421 (1980).

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