Process for the benign direct fixation and conversion of nitroge

Details Process for the benign direct fixation and conversion of nitroge Process for the benign direct fixation and conversion of nitroge

1999-01-15

2000-05-30

Dunn, Tom

Chemistry of inorganic compounds

Modifying or removing component of normally gaseous mixture

Nitrogen or nitrogenous component

4232391, 2521823, 25218212, 556422, 564107, 564112, B01D 5356, C07C24302, C07C24304

Patent

active

060688238

ABSTRACT:
A direct fixation of NO.sub.2 and N.sub.2 O.sub.4 at room temperature and atmospheric pressure is described using bis(diorganoamino)magnesium compounds formed from reactions between donor-solvent free diorganomagnesium compounds and primary or secondary amines, yielding new compositions of matter having the general formulas [(R.sub.2 N).sub.i (R.sub.2 NN.sub.x O.sub.y)jMg].sub.m and [(R.sub.2 N).sub.i (R.sub.2 NN.sub.x O.sub.y).sub.j (N.sub.x O.sub.y).sub.k Mg].sub.m. Methods are also described to convert these new compositions of matter into useful organic compounds and nitrogen gas.

REFERENCES:
patent: 3957823 (1976-05-01), Seebach et al.
patent: 4944894 (1990-07-01), Mehta et al.
patent: 5002689 (1991-03-01), Mehta et al.
patent: 5320774 (1994-06-01), Mehta et al.

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