Process for the asymmetric hydrogenation of a substituted acryli

Details Process for the asymmetric hydrogenation of a substituted acryli Process for the asymmetric hydrogenation of a substituted acryli

1975-06-25

1977-03-01

Raymond, Richard L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260295AM, 2603262, 2603405, 2603452, 2603458, 2603462R, 2603475, 260468R, 260468J, 260471R, 260471A, 260482R, 260514R, 260514J, 260518R, 260519, 260534R, 260690, C07B 100

Patent

active

040101819

ABSTRACT:
Optically active diphosphines of the formula, ##STR1## in which the phosphinomethyl groups are trans to each other, form rhodium complexes useful as catalysts in hydrogenating substituted acrylic acids and their esters to optically active propionic acid derivatives.

REFERENCES:
patent: 3798241 (1974-03-01), Kagan

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