Process for the application of IR spectroscopy for modulation an

Organic compounds -- part of the class 532-570 series – Organic compounds – Diazo or diazonium

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422 62, 422 68, 422108, 422110, 534558, 534560, 534565, 534579, 534581, 534582, C07C11304, C09D 2900, G01N 2134, G05B 1100

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047300370

ABSTRACT:
The invention relates to a method of determining and controlling the diazonium ion concentration in diazotization solutions and/or in azo coupling reactions, which comprises determining said diazonium ion concentration by means of IR spectroscopy from the intensity of the N.tbd.N stretching frequency.
The method is extremely selective and virtually trouble-free and permits the simultaneous determination of the concentration of different diazonium salts in mixtures.

REFERENCES:
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patent: 4159264 (1979-06-01), Hamilton et al.
patent: 4190578 (1980-02-01), Hamilton et al.
patent: 4234478 (1980-11-01), Atherton et al.
patent: 4268437 (1981-05-01), Behringer et al.
patent: 4439361 (1984-03-01), Karrenbauer et al.
Bailey, Control Engineering, Jan. 1982, pp. 78-80.
Reed et al, Chemical Abstracts, vol. 88, #58042y (1978).
Hesse et al., Spektroskopische Methoden in der Organischen Chemie, Georg Thieme Verlag 1984, p. 53.

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