Process for the anodic oxidation of aluminum and use thereof as

Chemistry: electrical and wave energy – Processes and products

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204 351, 204 383, 204 58, 2041291, 428329, 428339, 428934, 430278, C25D 544

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active

046081313

ABSTRACT:
In the process for the anodic oxidation of mechanically, chemically and/or electrochemically roughened aluminum or of one of its alloys, an aqueous electrolyte, which is free from H.sub.2 SO.sub.4 and contains H.sub.3 PO.sub.4 and Al.sup.+3 ions is used. The process parameters are: an electrolyte content of 25 g/l to 500 g/l of H.sub.3 PO.sub.4 and at least 5 g/l of Al.sup.+3 ions, a treatment time of 5 seconds to 500 seconds, a current density of 1 A/dm.sup.2 to 30 A/dm.sup.2 and a temperature of 35.degree. C. to 95.degree. C. The Al.sup.+3 ion source in particular is a salt of aluminum having a phosphoroxo anion, such as AlPO.sub.4. The material prepared in accordance with this invention is preferably employed as a support material for offset printing plates which carry a radiation-sensitive layer.

REFERENCES:
patent: 3511661 (1970-05-01), Rauner et al.
patent: 3594289 (1971-07-01), Watkinson et al.
patent: 3943039 (1976-03-01), Wittrock
patent: 4110147 (1978-08-01), Grunwald et al.
patent: 4211619 (1980-07-01), Usbeck
patent: 4229266 (1980-10-01), Usbeck
patent: 4277555 (1981-07-01), Fromson et al.
patent: 4396470 (1983-08-01), Atkinson
patent: 4409504 (1977-09-01), Chu et al.

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