Process for the anionic polymerization in the presence of crypta

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526191, 526204, 526205, 528 95, 528224, 528233, 528 14, 528239, 528314, 528358, 528368, 528371, 528379, 528409, 528413, 528424, 568679, C08F 446, C08F 450, C08G 6310, C08G 6512, C08G 7708, C08G 6362

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042244293

ABSTRACT:
A process for the anionic polymerization or copolymerization of olefinic monomers, dienic monomers, vinyl monomers and heterocyclic monomers is described which comprises reacting at least one monomer which is an olefinic monomer, a vinyl monomer or an heterocyclic monomer with a catalyst capable of inducing anionic polymerization and an aprotic macroheterocyclic cryptant, said at least one monomer being the only medium for the reaction.
The macroheterocyclic complexing agent has general formula ##STR1## in which: R.sub.1 is hydrogen, a hydrocarbon radical or alkoxycarbonyl, or the two R.sub.1 together can form a group of the general formula: ##STR2## in which A is a hydrocarbon radical,

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patent: 3890278 (1975-06-01), Lehn et al.
patent: 4116887 (1978-09-01), Lehn et al.
Bywater, "Anionic Polymerization", at pp. 27-30, 47-53, & 64-69, vol. 4, Progress in Polymer Science, Edited by A. D. Jenkins, Pergamon Press, Oxford & N.Y., 1974.

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