Process for the alkoxylation of organic compounds in the...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Reexamination Certificate

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C560S209000

Reexamination Certificate

active

10492192

ABSTRACT:
The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least one alkoxylating agent in the presence of a catalyst system, wherein a polyether alcohol is obtained. The catalyst system comprises a metallo organic framework mate-rial comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion. Furthermore it relates to polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

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S. Hayase, et al., “Polymerization of cyclohexene oxide with al(acac)3-silanol catalyst supported by zeolite and porous silica”, Journal of Polymer Science: Polymer Chemistry Edition, vol. 19, No. 10, pp. 2541-2550 1981.
Masakatsu Kuroki, et al., “(5,10, 15,20-Tetraphenylporphyrinato)manganese acetate as a novel initiator for the ring-opening polymerization of 1,2-epoxypropane”, Makromolekulare Chemie, vol. 189, No. 6, pp. 1305-1313 Jun. 1, 1988.
H. Li, et al., “Design and synthesis of an exceptionally stable and highly porous metal-organic framework”, NATURE, vol. 402, pp. 276-279 1999.

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